Product ID:849 5145,D-97 ASCORBIC ACID TANK AND REPLENISHER
MSDS Date:02/23/2000
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKFGM

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716 722 5151

Info Phone: 716-722-5151

Preparer: NOT PROVIDED.

Cage: 19139

EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES

ROCHESTER, NY 14650-3129 US

Telephone: 800-828-6203

Cage: 5K871

WATER

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL NOT PROVIDED.

ACGIH TLV: NOT PROVIDED.

SODIUM SULFITE

CAS: 7757-83-7

RTECS: WE2150000

OSHA PEL NOT APPLICABLE.

ACGIH TLV: NOT APPLICABLE.

SODIUM CARBONATE MONOHYDRATE

CAS: 5968-11-6

OSHA PEL NOT APPLICABLE.

ACGIH TLV: NOT APPLICABLE.

ASCORBIC ACID

CAS: 50-81-7

RTECS: CI7650000

OSHA PEL NOT APPLICABLE.

ACGIH TLV: NOT APPLICABLE.

DIETHYLENETRIAMINEPENTAACETIC ACID PENTASODIUM SALT

CAS: 140-01-2

OSHA PEL NOT APPLICABLE.

ACGIH TLV: NOT APPLICABLE.

SODIUM HYDROXIDE

CAS: 1310-73-2

RTECS: WB4900000

OSHA PEL 2 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NOT PROVIDED.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW
HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY
LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO
THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES
IRRITATION. SKIN: CAUSES IRRITATION. THIS MATERIA L HAS A LOW
POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN
SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF
SWALLOWED.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE. AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NONE. NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE
Effects of Overexposure:SULFUR DIOXIDE GAS IS IRRITATING TO THE
RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS
MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION.
SKIN: CAUSES IRRITATION. THI S MATERIAL HAS A LOW POTENTIAL TO
CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN
SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF
SWALLOWED.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST
TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GETMEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENT ION IF SYMPTOMS OCCUR. SKIN: IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH
CONTAMINATED C LOTHING BEFORE REUSE. DESTROY CONTAMINATED SHOES.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

Flash Point:NONE, NONCOMBUST
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT RELEVANT.

Handling and Storage Precautions:KEEP CONTAINER CLOSED.
Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH
EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING.

Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IFHAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED.RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION. IF RESPIRA TORS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:VENTILATION: GOOD GENERAL VENTILATION (TYPICALLY 10 AIR
CHANGES PER HOUR)SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:WEAR IMPERVIOUS GLOVES AND PROTECTIVE
CLOTHING APPROPRIATE FOR THE RISK OF EXPOSURE.
Work Hygienic Practices:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Supplemental Safety and Health
SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY
PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY
VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H
EATING, ETC.

HCC:B3
NRC/State Lic Num:NOT RELEVANT.
Boiling Pt:>100.C, 212.F
Vapor Pres:24 MBAR (18 MM HG
Vapor Density:0.6
Spec Gravity:(WATER = 1): 1.078
pH:10.46
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID COLOR: COLORLESS ODOR: NOT AVAILABLE
Percent Volatiles by Volume:90-95 %

Stability Indicator/Materials to Avoid:YES
NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY
REASONABLY COME INTO CONTACT
Stability Condition to Avoid:NOT PROVIDED.
Hazardous Decomposition Products:NONE
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.

Toxicological Information:INHALATION: EXPECTED TO BE A LOW HAZARD FOR
USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. IN
CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE
SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE
RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS
MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION.
SKIN: CAUSES IRRITATION. THIS MATERIA L HAS A LOW POTENTIAL TO
CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN
SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF
SWALLOWED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS:. POTENTIAL TOXICITY: FISH LC50 MG/L: >100
DAPHNID EC50 MG/L: >100 ALGAL IC50 MG/L: >100 ORGANICS READILY
DEGRAD ABLE (>70%): YES (7 DAYS) POTENTIAL BIOACCUMULATION: LOG
POW <1 COD (APPROXIMATE G/L): 20 BOD5 (APPROXIMATE G/L):
15 POTENTIAL TOXICITY WASTE TREATMENT MICROORGANISMS >100
EC5 0 (MG/L): AFTER DILUTION WITH A LARGE AMOUNT OF WATER,
FOLLOWED BY SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT
EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:UN NUMBER: NONE, NOT REGULATED. USA
DEPARTMENT OF TRANSPORTATION (DOT) HAZARDOUS MATERIALS
CLASSIFICATION: DOT (USA) STATUS: NOT REGULATED FOR OTHER
TRANSPORTATION INFORMATION, CALL THE KODAK WORLDWIDE
TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND
5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY.

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: NONE
Federal Regulatory Information:NOT PROVIDED.
State Regulatory Information:- MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE